141 : Goodbye..., Kurosaki -

: This event serves as the primary catalyst for the Hueco Mundo Sneak Entry arc , as Ichigo refuses to abandon her and sets out on a rescue mission against the orders of the Soul Society.

You can find more details on this specific episode and its manga counterpart on the Bleach Wiki . 141 : Goodbye..., Kurosaki

: In one of the series' most emotional moments, she delivers a heartfelt monologue, famously stating she wishes she could live five different lives so she could fall in love with the same person (Ichigo) five different times. : This event serves as the primary catalyst